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(f) use of high resolution ¹H NMR spectra (alongside the other spectral data specified in 2.(b) use of IR spectra in identification of chemical structure.Unit 2: ENERGY, RATE AND CHEMISTRY OF CARBON COMPOUNDS.The wavelengths which are absorbed to cause the vibrations (stretches and bends) will depend on the type of chemical bond and the groups or atoms at the ends of these bonds.Infrared radiation causes parts of a molecule to vibrate.Multiple functional groups may absorb at one particular frequency. ber of other publications all contain useful correlation charts. Alternatively, the total flow after the light pipe can be routed into a conventional. Infrared spectroscopy can be used to identify certain functional groups in an organic compound. mits the simultaneous generation of a normal chromatogram and the corresponding IR spectra for each chromatographic peak.Organic chemistry and instrumental analysis.eiii) deduction of the structures of organic compounds from different analytical data including: iii) IR spectra.Module 6: Organic chemistry and analysis.be able to use data from infrared spectra to deduce functional groups present in organic compounds and to predict infrared absorptions, given wavenumber data, due to familiar functional groups, including: C–H stretching absorption in alkanes, alkenes… Topic 7: Modern Analytical Techniques I.Students should be able to: use infrared spectra and the Chemistry Data Sheet or Booklet to identify particular bonds, and therefore functional groups, and also to identify impurities.‘Fingerprinting’ allows identification of a molecule by comparison of spectra.Bonds in a molecule absorb infrared radiation at characteristic wavenumbers. (It should be noted that these techniques are applicable not only to organic chemistry but also to many other areas of chemistry.) Brief reference to the principles of each method.Infra-red absorption spectrometry (IR) as a 'fingerprinting' technique involving absorption of infra-red radiation (reference to molecular vibrations not required).7.5 Chromatography and Instrumentation in Organic Chemistry.RSC Yusuf Hamied Inspirational Science Programme Go To: Top, IR Spectrum, References Data from NIST Standard Reference Database 69: NIST Chemistry WebBook The National Institute of Standards and Technology (NIST) uses its best efforts to deliver a high quality copy of the Database and to verify that the data contained therein have been selected on the basis of sound scientific judgment.Introductory maths for higher education.The physics of restoration and conservation. Also I tried to explain I was eating for one and not two or three people so did they have options for solo diners. The waitress obviously couldn’t understand me and kept asking if I wanted a hotpot. I wouldnt expect chicken and crab to cost the same. I assumed the wide selection of meats and vegetables had different pricing. I asked for an explaination of the menu and how things are priced. The waitress came up and with very limited English skills asked if I wanted a hotpot. Kind of like a melting pot establishment. Basically you pick a type of broth and various additions to cook at your table. In looking at the menu I was able to kind of understand the concept. The two menus are basically in Chinese with no clear prices. He said something in Chinese to a waitress behind him and she sat me at a table and tossed two menus on the table and walked away. I walked up to the front desk area with a young man who appeared to work there playing on his cell phone. There was one Asian family at a table and the rest of the place was empty. Went there at about 6:30pm on a week day and was surprised at how empty the place was. Saw the reviews for the place on my search engine and figured it looked pretty good and interesting as the reviews seemed to be overly positive. Was staying at one of the hotels with in walking distance of the restaurant. To Good Harvest - Post your score so customers can see and decide if they want to risk it- anything else is just deceptive. Hopefully there won't be any digestive repercussions but, if you skim the report and note the critical violations bolded in red, odds are, you'll wish you never went to Good Harvest. It was 78 - from less than 10 days ago!!!!! Had I seen that, we would have NEVER eaten there. But, imagine my shock when I looked up the sanitation score after i just had a feeling. I won't go in to detail on the process of ordering, it made no sense and no one was able to articulate it, they just kept saying all you could eat hot pot. If I'm trying a new place, I like to see it - heck, even if it's an old favorite - it's good to check once in a blue moon. Tried this place today for the first time and was a bit wary when I did not see the sanitation score/restaurant rating anywhere. Beware! If I could give a zero or negative score, I would. In most cases they sleep at night anyways as roughly 10 – 12 hours of sleep is required for a lovebird to remain in good health. Sometimes I’ve noticed them getting giddy just before they sleep but, they do sleep soon after. They’re rarely if ever loud at night so, if that’s a major concern of yours, I’d say don’t be too fused about it, either way you can place a cloth over the cage to stop the noise from being too irritating at night if they do suddenly tweet at night. I’ve owned lovebirds for over a year now and the only time they’ve been loud is when I went specifically to check in on them. After all lovebirds are very territorial, even amongst their own therefore, they will get very noisy to tell who ever is messing with them to back off. This could be to assert dominance over other birds or in attempt to protect their people, particularly their babies from other creatures. It’s also the way through which they communicate with us or in attempt to get their point across to others. It’s simply part of their nature to squeak at us and well, their natural chirping sounds are just designed to be loud. There are way to counteract this noisiness, one way includes covering the bird cage at night with a thicker cloth as it reduces the amount of noise that gets through. There are also other less pleasant reasons why they may get noisy, one reason being due to the passing of their mate whom they call out to at irregular times within the day or even at night and the other reason being due to fear.Īs other birds tend to get up in the morning just as the sun rises, lovebirds will normally get up around this time too as the noise stimulation from others outside singing triggers them to make some noise to follow suit. I’ve noticed that lovebirds tend be loudest throughout the morning hours, as they’re squeaking away to their partner, when singing or when trying to match the volume of the room (loud music, a TV show etc). Relative to other birds or parrots, lovebirds are far from the noisiest with an average decibel volume of 83 but, the high pitch noise they produce can leave your ear drums worse for wear.Ĭompared to dogs who bark at around 85 – 120 decibels or cats which are far quite purring around 25 decibels, these little chirpers are far from the loudest however, they do chirp a good more meaning, it’s less a matter of the lovebird being noisy over the the constant noise they produce. Lovebirds can get loud when chirping, so much so that they can even be heard through multiple walls. They were encouraged to call loved ones - “I suspect it was a way of showing were in control,” said Bulling. Meanwhile, on the ground, there was talk about sending a military airplane to “scramble” the United flight.īy 9:37, passengers were corralled past row 33. He turned the plane around, heading toward Washington, DC, and the Capitol building, which, according to Bulling, captured terrorists have identified as the target. Representing himself as the plane’s captain, he announced that he had a bomb. Deena Burnett A+E NETWORKSįive minutes into the takeover, terrorist Ziad Samir Jarrah (who had recently completed a piloting course) was in the cockpit and at the controls. “I was trying to think who you call for a hijacking,” she says in the documentary. He asked his wife to call authorities and report a hijacking. and told his wife, Deena, that a fellow passenger, Mickey Rothenberg, had been stabbed and murdered. They were both trained by al Qaeda in unarmed combat.įirst-class passenger Tom Burnett called home at 9:30 a.m. The forcefulness of the takeover leads Bulling to believe that Saeed al-Ghamdi and Ahmed al-Nami infiltrated the cockpit. “And then, radio silence.” Audio forensics specialist Ed Primeau A+E NETWORKS “It sounds like the pilot has been moved away from the controls,” Primeau says in the doc. “The Final Minutes” maintains that terrorists could have breached the locked cockpit with an extra key kept near the door. According to Primeau, two terrorists were struggling to take control of the cockpit. Minutes later, though, there were frantic calls of “Mayday! Mayday!” In short order, all planes were grounded, but Flight 93 was already en route to San Francisco.Īt 9:27, when Captain Jason Dahl checked in with Cleveland’s air traffic control, all was well. A+E NETWORKSįour minutes after Flight 93 had taken off - at 8:42 a.m., following a 40-minute delay - the first airplane flew into the World Trade Center. The 40 passengers and crew members, all of whom died, will be honored Friday when President Trump and Democratic nominee Joe Biden both pay their respects at the site of the Flight 93 National Memorial in Shanksville.Īs laid out in the documentary, here is a minute-by-minute chronicle, with freshly revealed details, of what took place aboard an airplane set on a collision course with the heart of our nation. “They fought against the odds to stop an airplane from crashing into the Capitol building.” “What those people did was such an amazing act of courage,” Bulling told The Post. Instead, as they fought for control, the plane crashed into a field near rural Shanksville, Pa., at 10:03 a.m.ĭuncan Bulling, director of the documentary, worked with audio forensics specialist Ed Primeau to analyze cockpit recordings that give a fuller picture of what happened. Heroic Americans, they stopped terrorists from flying into the Capitol building. on History, the bravery of passengers and crew aboard the United Airlines flight from Newark to San Francisco prevented death, heartache, destruction. As chronicled in “ History 9/11: The Final Minutes of Flight 93,” airing Friday at 8 p.m. 'Transformers' movie trailer reminiscent of 9/11 gets pulled from social mediaįour commercial jets were hijacked on September 11. What is PIF? The Saudi investment fund behind PGA Tour and LIV Golf's merger Outraged 9/11 families feel 'completely betrayed' by PGA Tour over LIV Golf merger PGA Tour board member vows to 'kill' anyone involved in 9/11 attacks himself after LIV merger Sportsurge is a flagship sports streaming platform which delivers live and on-demand coverage of some of the most popular sports in North America. They offer both live streaming and archived games for your convenience so you'll never miss an important game no matter what situation you find yourself in. The best thing about Sportsurge is that it's 100% free for users no subscriptions are required to use the service. Sportsurge offers various channels like NFL, NHL, NBA, Boxing and MMA that you can stream live on your device or TV through AirPlay or Chromecast. Sportsurge is a free platform where you can catch all the latest sporting events. They provide real-time statistics, information, and player profiles for fans who want to watch their favorite game. Sportsurge is a leading sports data and content company that allows users to watch games through their platform. It provides live streams of NFL, NHL, NBA, Boxing and MMA sports to fans in over 150 countries. Sportsurge is the world's first mobile sports streaming app. All you have to do is just visit the site and find your desired sport. It offers free streams of any game in NFL, NBA, MMA, and Boxing. Sportsurge is a live streaming website which provides users with the opportunity to watch sports matches. All you need is a smartphone and internet connection and you’re all set! What is Sportsurge? With Sportsurge it’s easier than ever to catch your favorite sports event live. It includes in-app navigation features such as Chromecast support and sharing options like Facebook Live and Twitter Direct Message. The app’s interface is uncomplicated and easy to use. Sportsurge also provides an android app that was recently updated to work seamlessly with the newest Android Pie operating system. All you need is a smartphone and internet connection and you’re all set! You can use it to stream cricket, football, baseball and more. Eastern on Saturday, with full streaming details available below.Sportsurge is an app which lets you stream any sport you want to watch. Quarterback Jake Luton suffered a scary thoracic spine fracture in Oregon State’s last game against Washington State, leaving the starting job in the hands of Utah State transfer Darell Garretson. Running back Ryan Nall can still cause some damage, as the talented junior is averaging 6.1 yards per carry with four touchdowns. 2 but have been blown out in their three contests against FBS competition. Oregon State did manage a win over Portland State back on Sept. Gary Andersen has quite a rebuilding job on his hands, as the Beavers are off to a 1-3 start and haven’t shown any improvement from last year. Watch NCAA Football for FREE on fuboTV: Watch over 67 live sports and entertainment channels with a 7-day FREE trial! Washington’s defense is also wrecking people once again to the tune of 11.8 points allowed per game, leaving a growing injury list as Chris Petersen’s top concern. Junior running back Myles Gaskin leads a deep backfield and went off for a career-high 202 yards against the Buffaloes. The Huskies largely breezed through an easy nonconference slate and impressively dismantled Colorado 37-10 last Saturday in Boulder. Washington entered the 2017 season as one of the national favorites to make a repeat run to the College Football Playoff, and have looked good in the early going. 6 Washington Huskies will look to continue their perfect start to the season when they visit the Oregon State Beavers on Saturday night at Reser Stadium. Yao will go down as one of my favorite players ever and I am so glad that I got to see him play LIVE, in his prime. And it's so sad that we were robbed of an all-time great. If you are a fan of great centers, then you have to be a fan of Yao Ming. Ming Yaos full details including attributes, animations, tendencies, coach boosts, upgradable badges, evolutions (stats and badge upgrades), dynamic duos, and comments. There was NO ONE in the league at the time that could really go to war with Shaq, and Yao proved that he could hold his own, right off the bat. His rookie season battle with Shaq was simply EPIC. I'd take a healthy Yao Ming over ANY center in the NBA today, no question. Yao benefited greatly from working with Patrick Ewing during his formative years in Houston, and also working with Hakeem. He had a silky smooth jump shot, he could hit his free throws, AND he had a vast array of post moves. He was very agile/mobile for being 7'6" (name another center taller than 7'5" that was as athletic as Yao. He's definitely deserving of it, either way. The entire country of China became interested in basketball once Yao was drafted into the NBA. Even so, Yao is a guaranteed Hall of Famer, because of his contributions to the sport. He's one of the best big men to ever play the game, but unfortunately, injuries derailed what should've been a monumental career. If Yao could've stayed healthy, there's NO DOUBT in my mind that he would STILL be a top 3 center in the NBA, if not the #1 center. He was pretty awesome and if Shaq had been in the east we all would have heard more about him and you kids would have gotten to see him more on sports center. I just watched that Yao hype video and it showed him giving great effort in competing agains Shaq but if any of you are old enough to have actually watched the games you would agree that yes Yao was friggin super human at that size and was a pretty mobile big for that over sized stature but unfortunately he had a more "Dominant" big preventing him from getting the opportunity to be talked about the way he should have been. He was pretty awesome to watch simply towering over every big man in the game at that time, however as with most abnormal giants he didnt have a strong enough solid base to seriously compete against his conference rival. I really wish he had not suffered so many injuries because it would have been very exciting for many to see him continue to get dominated by Shaq lol. He was extremely tough to try and move him off his base when he went camel spread with those legs. Mylie10 wrote:It's sad that Yao got robbed of a great career with injuries. VA, or WA, the Provider of this Plan and the entity responsible for fulfilling the terms of this Plan is Dealers Alliance Corporation, 240 N. Fifth Street, Suite 350, Columbus, OH 43215.If you purchased this Plan in AZ, NC, NM, OK, Is Dealers Assurance Company (License # 02977), receiving mail at 240 N. Number of chairs: two (2) Seat dimensions: 17 inches long x 18.5 inches wide x 19.75 inches high. If you purchased this Plan in Florida, the Provider of this Plan and the entity responsible for fulfilling the terms of this Plan Constructed of Asian rubberwood, the Calista dining chairs are sturdy and long-lasting with 100-percent density foam padding for a comfortable place to entertain. Box 11355, West Palm Beach, Florida 33419. NV, NY, OH, OR, PA, RI, SC, SD, TN, TX, UT, VT, WI, WV, the Provider of this Plan and the entity responsible for fulfilling the terms of this Plan is Tarmo, LLC,ħ77 South Flagler Drive, West Palm Beach, Florida, 33401, receiving mail at P.O. If you purchase this Plan in the following states, AL, AK, CA, CO, CT, DE, DC, GA, IA, ID, IL, IN, KS, KY, LA, MD, MA, ME, MI, MN, MO, MS, MT, NE, ND, NH, NJ, You can rest easy-they've got you covered. Should your furniture, area rug, or mattress need cleaning or repairs, We've partnered with Uniters* to provide you with best-in-class Protection Plan options. /rebates/2fp2fSAFAVIEH-Lester-Gray-Zebra-Dining-Chair-Set-of-2-MCR4709Q-SET22f204784103&. Animal Print Cushions for Your Dining Chairs, Wood Chair Chairpads with Foam Inserts 5 out of 5 stars (40) Sale Price 34. Any previous claims or an administrative fee may be deducted from your refund. Zebra Dining Chairs (1 - 40 of 85 results) Price () Any price Under 250 250 to 750 750 to 1,500. After 30 days, your refund will be prorated. Will I have to pay a deductible? Nope! Can I cancel my plan? You can cancel your plan for a full refund within 30 days of purchase. How do I submit a claim? You can submit a claim to Uniters on their website or app, or give them a call at the phone number listed on your Protection Plan certificate. What isn't covered by this plan? See full list of exclusions. It also does not cover damages caused by natural disasters such as a fire or flooding, or furniture used in commercial settings. 1-48 of over 7,000 results for 'zebra print chairs' Results Price and other details may vary based on product size and color. What isn't covered by this plan? This plan does not cover damages caused by accumulation, neglect, abuse, or failure to comply with the manufacturer’s warranty. Once I've purchased a plan, when does my coverage begin? Coverage for accidental damage begins the day your product is delivered. What's covered under "accidental damage? In terms of accidental damage, this plan covers all unintentional stains, rips, tears, burns, punctures, gouges, chips, dents, and water rings. Enjoy the comfort of premium coverage with a Uniters Protection Planįrequently Asked Questions What does this Protection Plan cover? This plan covers all accidental stains as well as accidental damage to your furniture. Dining Room > Luna Brown Zebra Wood Veneer Lacquer Sideboard/Buffet. I'm not sure exactly what the draw bar forces are exactly for different integrexes i.e. other than the rotational repeatability that -MariTool- mentioned. (smaller machines and smaller in cut loads seems HSK would suffice. Maybe what is getting at is the NEW KM4X interface ~ which apparently (HSK) machines can be retrofitted for ?īasic draw bar force for comparison of the different connections can make a real difference. KM is also an option offered even for new machines as an option. Not really the case any more.įor new / newer MAZAK integrex(es) for some reason they offer HSK as standard and Capto (in the case of a C-6 machine ) is about a $4000 upgrade factory ordered for a new build. Years gone by it was almost mandatory to have a lower turret on a b axis machine to be able to hold tolerances on turned features (so I'm told). I think it's becoming more common to specify machines in this configuration generally, as the technology improves. Doing everything on the b axis head keeps everything simple and flexible at the cost of production efficiency. We specified our NTX without a lower turret because the most important criteria to us was quick changeovers for one-two off parts. HSK also can't be used for building modular tool assemblies, whereas Capto excels at that too. HSK may be easier to balance for very high speeds compared to Capto, but I think that is even marginal tbh. HSK rules in milling spindles because it provides all the benefits of Capto that matter in that scenario, while being a much cheaper spindle to make, and cheaper tools to buy. I think what it boils down to is that HSK doesn't have any direct benefits over Capto beyond cost. Those are solid arguments and all totally correct. The options for milling holders are probably greater on HSK, but I've never struggled to get what I need on Capto.Ĭapto holders are generally a bit more expensive than HSK holders, all else being equal, so you need to consider that.Ĭapto is pretty much the de-facto standard on all new millturns these days anyway, and is now an ISO standard (ISO 26623, generally called PSC) rather than being a proprietary Sandvik product, which means that there are many manufacturers of Capto/PSC tools now.Īvoid KM at all costs, it is an orphaned system that never saw wide scale adoption by anybody except Mazak on early integrexes, and while Kenna still make it, you have to wonder whether they will continue to do so for very long. The options for turning tools are much greater on Capto than on HSK-T. HSK-T is a bit of a kludge that was developed to try and match Capto for torsional rigidity and repeatability, but it falls short on both. It's just as good as HSK for milling, and much better for turning. NOTE: It is not recommended that existing Parallels Desktop for Mac users move to Parallels Desktop App Store Edition. Parallels Desktop Installation Assistant helps you to get up and running in a few minutes. Powerful performance lets you run many Windows apps on your Mac, including games and CAD programs. Download and install Windows in two clicks. Share Mac folders with Windows-including Desktop, Documents, and Downloads. NEW: Drag and drop text or graphics between macOS and Windows apps. NEW: Enhanced desktop, video, and gaming experience with a higher refresh rate. NEW: Use the Trusted Platform Module 2.0 device in Windows. 3D graphics acceleration up to DirectX® 11.1. Copy/paste formatted text and files between macOS, Windows, and Linux. Drag and drop files and images between macOS, Windows, and Linux. Resize the window to get the desired Windows or Linux resolution. Connect USB devices to Windows and Linux. Creating and editing virtual machine configurations is available for free. Running virtual machines requires an in-app purchase of an auto-renewable subscription (1 year). There is a fully functional 14-day trial to test Parallels Desktop before the subscription starts. On a Mac with an Intel processor, you can run most Windows, Linux, and macOS versions. NOTE: See the full list of supported operating systems and system requirements at On a Mac with the Apple M1 chip, you can run Windows 10 (and Windows 11) on ARM Insider Preview, Ubuntu Linux, Fedora Linux, Debian GNU/Linux, and Kali Linux (all ARM-based versions). If you have any feedback, problems, or concerns, please contact us at We want you to be completely satisfied with Parallels Desktop. It says I can run Windows and hense its apps. |